Chemistry 111           Summer 2009
Instructors:   Required Materials:
Tom Whelan
ISB 149E, 545-6092
whelan@chem.umass.edu 		  Textbook:  
Chemistry & Chemical Reactivity,7th Edition.

Kotz, Treichel & Townsend.
  1. Class Meets:  MTuWThF 11:15-12:45
  2. Class Location:  ISB 221
  
  1. Safety Glasses:
    American Optical Co. No. 484A.
  2. Scientific Calculator 



Ayga Frimpong
afrimpong@chem.umass.edu 		 


Eun Shin
eshin@student.umass.edu
     



Aruni Karunanayake
akarunan@chem.umass.edu 		 
   
Acknowledgement  



Prof. William Vining at SUNY Oneonta, many of his interactive modules I have links to on this web page.  To see a host more of these and find out what Bill was up to in the picture on the left ... just click on the image! 
 
Syllabus Summary:
  1. Grading
    3 Exams 70% Highest Exam Score 26%; Lowest 20%; Other 24%
    Quizzes 10% No make-up Quizzes given.
    Laboratory 20%
  2. Exam Policies:
    You must have a passing exam average  in order to pass the course. 
  3. Lab Policies:
    Lab Meets Tuesday/Thursday, 1:30-4:30, ISB 155.
    You must complete all of the laboratory experiments to pass the course.
  4. Academic Honesty:
    You will abide by the academic honesty policy of the campus.  I expect you to do your own work on exams and labs.  You mush flush all calculator memories of any chemistry information before coming to an exam.  You MAY NOT bring any additional materials to exams other than a pencil, calculator, and your brain.  I take honesty very seriously.  
  5. Grade Cutoff's:
    >90's  A.                <55 F
    The other grade cutoff's will be determined at the end of the semester.  However if you want to be assured of a B you should be in the 80's and 70's for a C.
  6. Exam Dates:
    Exam III Thursday Jul 09 11:15-12:45 ISB 221
  7. Old Exams
    2007 Exam I Key I Exam II Key II Exam III Key III
    2006 Exam I Key I Exam II Key II Exam III Key III
Date Daily Schedule ... Updated Sunday, November 09 :- 01:27 PM
Thursday
Jul 09		 Exam III
Wednesday
Jul 08
 
Lecture 25
Slides		 Lecture Material:
Exam III Review
 
Homework:
 
Announcements:
1.. Exam III - Thursday, July 09, In Class 
3 or 4 Questions from the following Lab Owls:-  
LO-3.3, LO-4.2, LO-4.5, LO-5.1, LO-5.5
Tuesday
Jul 07
 
Lecture 24
Slides		 Lecture Material:
11.6 The Kinetic and Molecular Theory of Gases
LO Stoichiometry Review
  
Homework:
OWL 11.6a Simulation: Kinetic and Molecular Theory 07-08-09
11.6e Homework: Kinetic Theory - Qualitative 07-08-09
Lab 111 TA Evaluation 07-08-09
 
Announcements:
1. Last Lab Session - Today, July 7, 1:30-4:30, ISB 155
2. Exam III - Thursday, July 09, In Class 
3 or 4 Questions from the following Lab Owls:-  
LO-3.3, LO-4.2, LO-4.5, LO-5.1, LO-5.5
Monday
Jul 06
 
Lecture 23
Slides		 Lecture Material:
5.7 Enthalpy Calculations
  Hess's Law and Heats of Formation
11.6 The Kinetic and Molecular Theory of Gases
Quiz 17
 
Homework:
OWL 5.7c Tutor: Enthalpy of Formation 07-07-09
5.7d Homework: Enthalpy of Formation 07-07-09
 
Announcements:
1. Last Lab Session - Tuesday, July 7, 1:30-4:30, ISB 155
2. Exam III - Thursday, July 09, In Class 
3 or 4 Questions from the following Lab Owls:-  
LO-3.3, LO-4.2, LO-4.5, LO-5.1, LO-5.5
Friday
Jul 03		 No Class
Thursday
Jul 02
 
Lecture 22
Slides		 Lecture Material:
5.6 Determining the Heat Transfer in a Chemical Reaction
  Calorimetry
5.7 Enthalpy Calculations
  Hess's Law
     
Homework:
OWL 5.5b Tutor: Enthalpy Changes 07-06-09
5.5c Homework: Thermochemical Stoichiometry 07-06-09
5.6c Simulation: Calorimetry 07-06-09
5.6d Homework: Calorimetry 07-06-09
5.7a Simulation: Hess's Law 07-06-09
5.7b Homework: Hess's Law 07-06-09
 
Announcements:
1. No Class - Friday, July 3rd.
Wednesday
Jul 01
 
Lecture 21
Slides		 Lecture Material:
5.2 Specific Heat Capacity
  Heat Transfer ... Heat Capacity
5.4 The First Law of Thermodynamics
  Enthalpy ... A Special Type of Heat Transfer
     
Homework:
OWL 5-2b Simulation: Temperature Change/Heat Transfer 07-02-09
5-2c Tutor: Specific Heat Capacity 07-02-09
5-2d Tutor: Heat Equilibrium 07-02-09
5-2e Homework: Specific Heat Calculations 07-02-09
 
Announcements:
Tuesday
Jun 30
 
Lecture 20
Slides		 Lecture Material:
3.7 Acids and Bases
  Strong and Weak Acids and Bases
  Reactions of Acids and Bases
  Strong Acid + Strong Base - NIE
  Weak Acid + Strong Base - NIE
3.8 Gas-Forming Reactions
  Metal Carbonates + Strong Acid - NIE
  Metal Carbonates + Weak Acid - NIE
  Types of Gas Forming Reactions
3:10 Classifying Reactions in Aqueous Solution
5.1 Energy: Some Basic Principles
Quiz 14
    
Homework:
OWL 3.7b Simulation: Acids 07-01-09
3.7c Homework: Strong/Weak Acids 07-01-09
3.7e Homework: NIE - Acid/Base Reactions 07-01-09
3.8 Homework: Gas Forming Reactions 07-01-09
5.1d Tutor: Energy Unit Conversions 07-01-09
5.2b Simulation: Temperature Change and Heat Transfer 07-01-09
 
Announcements:
1. No Class -- Friday, July 3rd.
Monday
Jun 29
 
Lecture 19
Slides		 Lecture Material:
3.5 Ions and Molecules in Aqueous Solution
  The Dissolution Process ... Example I ... Example II 
  Solubility of Ionic Compounds in Water
  Solubility Guidelines
3.6 Precipitation Reactions
  Predicting the Outcome
  Net Ionic Equations
     
Homework:
OWL 3-5e Tutor: Solubility Strong Electrolytes 06-30-09
3-5c Homework: Strong Electrolytes 06-30-09
3-6c Tutor: Precipitation Reactions 06-30-09
3-6d Tutor: Net Ionic Equations 06-30-09
3-6e Homework: Net Ionic Equations I 06-30-09
3-6f Homework: Net Ionic Equations II 06-30-09
 
Announcements:
Friday
Jun 26
 
Lecture 18
Slides		 Lecture Material:
9.1 Orbitals and Theories of Chemical Bonding
9.2 Valence Bond Theory
  Hybridization ... Sigma Bonds ... Methane
  Hybridization ... Multiple Bonds ... Ethene
   Hybridization ... Allene ... Benzene
   Pi Molecular Orbitals In Ethene
   Seeing is believing!!
 
Homework:
OWL 9-2a Tutor: Sigma Bonding 06-29-09
9-2e Tutor: Determining Hybrid Orbitals 06-29-09
9-2i Tutor: Hybridization 1 06-29-09
9-2j Tutor: Hybridization 2 06-29-09
9-2n Tutor: Pi Bonding 06-29-09
9-2f Homework: Hybrid Orbitals 06-29-09
9-2g Homework: Identifying Sigma Bonds 06-29-09
9-2o Homework: Pi Bonding 06-29-09
 
Announcements:
Thursday
Jun 25		 Exam II
Wednesday
Jun 24
 
Lecture 17		 Lecture Material:
Exam II Review
 
Homework:
 
Announcements:
1. Exam II -- Thursday, June 25, In Class.
Tuesday
Jun 23
 
Lecture 16
Slides		 Lecture Material:
8.7 Molecular Polarity
  Electronegativity Values
   Intermolecular Forces ... Class Handout ... Hydrogen Bonds
Quiz 12
 
Homework:
OWL 8-8a Exercise: Determining Polarity of a Molecule 06-24-09
8-8b Homework: Molecular Polarity 06-24-09
 
Announcements:
1. Fourth Lab Session -- Today, June 23, 1:30-4:30, ISB 155
Monday
Jun 22
 
Lecture 15
Slides		 Lecture Material:
8.6 Molecular Geometry 
  Molecular Geometry Worksheet
   Summary ... No Lone Pairs
  Summary ... Lone Pairs
Quiz 11
 
Homework:
OWL 8-6c Tutor: Ideal Shapes 06-23-09
8-6d Tutor: Determining Molecular Shapes 06-23-09
8-6e Exercise: Determining Molecular Shapes 06-23-09
8-6f Homework: Molecular Geometry 06-23-09
 
Announcements:
Friday
Jun 19
 
Lecture 14
Slides		 Lecture Material:
8.5 Lewis Dot Structures
  Beyond the Octet ... What to do with 'Extra' Electrons
  Some Exceptions and Some Organic Molecules
8.9 Bond Properties
  Bond Order ... Bond Length
   Bond Length and Resonance
  Bond Energies
8.3 Evaluating Lewis Dot Structures
  Formal Charge
  Formal Charge Vs Oxidation Numbers
   
Homework:
OWL 8-5a Tutor: Exceptions to the Octet Rule 06-22-09
8-5d Homework: Interpreting Lewis Structures 06-22-09
8-9a Homework: Bond Order, Length, Strength 06-22-09
8-9c Homework: Bond Energy and Enthalpy of Reaction 06-22-09
8-3a Tutor: Formal Charge 06-22-09
8-3b Homework: Formal Charge 06-22-09
 
Announcements:
Thursday
Jun 18
 
Lecture 13
Slides		 Lecture Material:
8.2 Lewis Dot Structures
   Lewis Dot Worksheet
   Dealing With Charges
  Shortage of Electrons ... Multiple Bonds
8.4 Lewis Dot Structures
  Choices in Multiple Bond Formation ... Resonance
 
Homework:
OWL 8-4a Tutor: Resonance Structures 06-19-09
8-4b Homework: Resonance Structures 06-19-09
 
Announcements:
Wednesday
Jun 17
 
Lecture 12
Slides		 Lecture Material:
7.5 Periodic Trends
  Orbital Energy            Atomic Size 
  Ionization Energy        Electron Affinity 
8.2 Lewis Dot Structures
  Bond Formation Pro's and Con's
  Lewis Dot Worksheet
   Bond Pairs Vs Lone Pairs
 
Homework:
OWL 7-5b Homework: Atomic Size 06-18-09
7-5d Simulation: Ionization Energy 06-18-09
7-5e Homework: Ionization Energy 06-18-09
7-5f Simulation: Electron Affinity 06-18-09
7-5g Simulation: Ion Charge 06-18-09
8-2b Tutor: Interpreting Lewis Structures 06-18-09
8-2c Exercise: Drawing Lewis Structures 06-18-09
8-5c Tutor: Drawing Lewis Structures 06-18-09
 
Announcements:
Tuesday
Jun 16
 
Lecture 11
Slides		 Lecture Material:
7.3 Atomic Electronic Configurations
  Completed Electronic Configurations Worksheet 
  Magnetism ... Paramagnetic Vs Diamagnetic
   Electronic Configuration; Orbital Box
  More Electronic Configurations ... Transition Metals
7.4 Atomic Electronic Configurations ... Ions
7.5 Periodic Trends
  Orbital Energy 

Na and Water

K and Water

Na and Water!!
 
Homework:
OWL 7-4e Homework: Para/Diamagnetic 06-17-09
7-3g Homework: Electron Configurations 06-17-09
7-4a Simulation: Electron Configurations of Ions 06-17-09
7-5c Simulation: Orbital Energies 06-17-09
7-5a Simulation: Atomic Size 06-17-09
 
Announcements:
1. Third Lab Session -- Today, June 16, 1:30-4:30, ISB 155
Monday
Jun 15
 
Lecture 10
Slides		 Lecture Material:
7.3 Atomic Electronic Configurations
  Electronic Configurations Worksheet
  Orbital Energies
  Pauli Exclusion Principle  
  Electronic Configuration; Spectroscopic
  Noble Gas Configurations ... Why?
  Valence Electrons ... Group Number ... Preferred Charge
  Magnetism ... Paramagnetic Vs Diamagnetic
   
Homework:
OWL 7-3a Simulation: Electron Configurations of Atoms  06-16-09
7-3d Tutor: Electron Configurations 1 06-16-09
7-3f Tutor: Electron Configurations 2 06-16-09
7-4d Tutor: Configurations and Magnetism 06-16-09
  
Announcements:
Friday
Jun 12		 Exam I
Thursday
Jun 11
 
Lecture 9		 Lecture Material:
Exam I Review
 
Homework:
 
Announcements:
1. Second Lab Session -- Today, June 11, 1:30-4:30, ISB 55
Wednesday
Jun 10
 
Lecture 8
Slides		 Lecture Material:
6.5 Modern Quantum Theory
  Heisenberg Uncertainty Principle
  Edwin Schrodinger
6.6 The Shapes of Atomic Orbitals 
  Solutions of Interest to the Schrodinger Equation
   The Orbitron!
  Orbital Shapes  
  Orbital Shapes with Increasing n
 
Homework:
OWL 6-6a Exercise: Orbital Shapes 06-11-09
6-6b Homework: Shapes of Atomic Orbitals 06-11-09
 
Announcements:
Tuesday
Jun 09
 
Lecture 7
Slides		 Lecture Material:
6.2 Energy and Photons
  Energy/Wavelength/Frequency
   Energy/Wavelength/Frequency data and Relationships
6.4 Particle-Wave Duality
  Louis de Broglie
6.5 Modern Quantum Mechanics
  Standing Wave Animation 
  Heisenberg Uncertainty Principle
  Edwin Schrodinger
 
Homework:
OWL 6-1c Tutor: Determining Frequency 06-10-09
6-1d Tutor: Determining Wavelength 06-10-09
6-2c Tutor: Energy of Light 06-10-09
6-2d Homework: Energy of Light 06-10-09
 
Announcements:
1. First Lab Session -- Today, June 09, 1:30-4:30, ISB 155
Monday
Jun 08
 
Lecture 6
Slides		 Lecture Material:
3.2 Balancing Chemical Equations

C60 and beyond.

Mg +CO2!
6.1 Introduction to Electromagnetic Radiation
  Wave Properties
  Electromagnetic Spectrum
6.2 Energy and Photons
  Energy/Wavelength/Frequency
   Energy/Wavelength/Frequency data and Relationships
Prof. David Phillips
"A Little Light Relief" 
 
Homework:
OWL 3-2c Tutor: Balancing Chemical Equations 06-09-09
3-2d Homework: Balancing Chemical Equations 06-09-09
6-1a Simulation: The Electromagnetic Spectrum 06-09-09
6-2b Simulation: Planck's Constant 06-09-09
  
Announcements:
1. Labs Start, Tuesday, June 9. 
Friday
Jun 05
 
Lecture 5
Slides		 Lecture Material:
2.9 Formulas, Compounds, and the Mole
  Molar Mass (Molecular Weight)
2.10 Describing Compound Formulas
  Formula to Percent Composition
  Percent Composition to Formula
  Empirical Formula Vs Molecular Formula
3.2 Balancing Chemical Equations
Quiz 4
   
Homework:
OWL 2-9c Tutor: Determining Molar Mass  06-08-09
2-9e Tutor: Using Molar Mass 1  06-08-09
2-9f Tutor: Using Molar Mass 2  06-08-09
2-9g Homework: Mole Calculations 1 06-08-09
2-10a Tutor: Percent Composition 06-08-09
2-10b Homework: Percent Composition 06-08-09
2-10d Tutor: Empirical Formula 06-08-09
2-10e Tutor: Molecular Formulas 06-08-09
2-10f Homework: Empirical/Molecular Formulas 06-08-09
 
Announcements:
Thursday
Jun 04
 
Lecture 4
Slides		 Lecture Material:
2.7 Ionic Compounds
Formula and Name
  Metal + Non metal
  Metal + Polyatomic anion
  Transition Metals
2.9 Atoms, Molecules, and the Mole
  Molar Mass (Molecular Weight)
 
Homework:
OWL 2-7i Simulation: Ionic Compounds 6-05-09
2-7l Tutor: Naming Ionic Compound Formulas 6-05-09
2-7k Homework: Naming Ionic Compounds 6-05-09
2-9a Tutor: Moles and Atoms Conversions 6-05-09
2-9b Homework: Mole/Particle Conversions 6-05-09
 
Announcements:
Wednesday
Jun 03
 
Lecture 3
Slides		 Lecture Material:
2.5 Introduction to the Periodic Table
  Divisions in the Periodic Table
2.7 Ionic Compounds
Properties ... Coulomb's Law
  Coulomb's Law Data
   Coulomb's Law and Solubility
 
Homework:
OWL 2-5a Exercise: Periodic Table Organization 6-04-09
2-5b Homework: The Periodic Table 6-04-09
2-7m Simulation: Coulomb's Law 6-04-09
 
Announcements:
Tuesday
Jun 02
 
Lecture 2
Slides		 Lecture Material:
2.7 Ionic Compounds
Nomenclature  ... Some Memorization 
2.1 Atomic Structure
2.2 Atomic Number and Atomic Mass
2.3 Isotopes
  Determining the exact mass of an isotope
2.4 Atomic Weight ... What is it? 
 
Homework:
OWL R-3h Tutor: Unit Conversion 6-03-09
R-3a Tutor: Scientific Notation 1 6-03-09
R-3b Tutor: Scientific Notation 2 6-03-09
R-3c Tutor: Scientific Notation 3 6-03-09
R-3d Homework: Scientific Notation 6-03-09
2-7c Tutor: Ions, Predicting Charge 6-03-09
2-7g Tutor: Polyatomic Ions 6-03-09
2-2b Tutor: Atomic Composition 6-03-09
2-2c Homework: Atomic Composition 6-03-09
2-4b Homework: Atomic Mass 6-03-09
 
Announcements:
Monday
Jun 01
 
Lecture 1
Slides		 Lecture Material:
Course Policy and Expectations!
  Lab Announcements
The Computer Resource Center
  Introduction to Owl
A Small Tour of Integrated Sciences Building
R.3 Mathematics of Chemistry: 
Dimensional Analysis
Scientific Notation
Significant Figures
     How Important Are Units?
 
Homework:
OWL Intro to Owl Navigation, Messages, and Browsers 6-02-09
Intro to Owl Question Types in OWL 6-02-09
Intro to Owl Formulas, Scientific Notation, and Tables 6-02-09
Math Exponents 6-02-09
Math Basic Algebra 6-02-09
R-3e Homework: Significant Figures 6-02-09

Announcements:
1. Daily Quizzes -- Start tomorrow, June 2.