Chemistry 111           Summer 2010
Instructors:   Required Materials:
Tom Whelan
ISB 241E, 545-6092
whelan@chem.umass.edu 		  Textbook:  
Chemistry & Chemical Reactivity,7th Edition.

Kotz, Treichel & Townsend.
  1. Class Meets:  MTuWThF 11:15-12:45
  2. Class Location:  ISB 221
  
  1. Safety Glasses:
  2. Scientific Calculator 



Chengbei Li
cli@chem.umass.edu 		 


Ben March
bmarch@student.umass.edu
     



Travis Softic
tsoftic@student.umass.edu 		 


Nan Wang
nan@chem.umass.edu
   
Acknowledgement  



Prof. William Vining at SUNY Oneonta, many of his interactive modules I have links to on this web page.  To see a host more of these and find out what Bill was up to in the picture on the left ... just click on the image! 
 
Syllabus Summary:
  1. Grading
    3 Exams 70% Highest Exam Score 26%; Lowest 20%; Other 24%
    Quizzes 10% No make-up Quizzes given.
    Laboratory 20%
  2. Exam Policies:
    You must have a passing exam average  in order to pass the course. 
  3. Lab Policies:
    Lab Meets Tuesday/Thursday, 1:30-4:30, ISB 155.
    You must complete all of the laboratory experiments to pass the course.
  4. Academic Honesty:
    You will abide by the academic honesty policy of the campus.  I expect you to do your own work on exams and labs.  You mush flush all calculator memories of any chemistry information before coming to an exam.  You MAY NOT bring any additional materials to exams other than a pencil, calculator, and your brain.  I take honesty very seriously.  
  5. Grade Cutoff's:
    >90's  A.                <55 F
    The other grade cutoff's will be determined at the end of the semester.  However if you want to be assured of a B you should be in the 80's and 70's for a C.
  6. Exam Dates:
    Exam I Friday June 18 11:15-12:45 ISB 221
    Exam II Wednesday June 30 11:15-12:45 ISB 221
    Exam III Tuesday July 13 11:15-12:45 ISB 221
  7. Old Exams
    2007 Exam I Key I Exam II Key II Exam III Key III
    2006 Exam I Key I Exam II Key II Exam III Key III
Date Daily Schedule ... Updated Sunday, November 09 :- 01:27 PM
Tuesday
Jul 13		 Exam III - In Class
Monday
Jul 12
 
Lecture 20
Slides		 Lecture Material:
LO Stoichiometry Review
Exam III Review
 
Homework:
OWL TA Evaluation 07-13-10
 
Announcements:
1. Exam III, Tuesday, July 13, In Class
3 to 4 Q's from  Lab Owls:-  LO-3.3, LO-4.2, LO-4.5, LO-5.1, LO-5.5
Friday
Jul 09
 
Lecture 19
Slides		 Lecture Material:
5.7 Enthalpy Calculations
  Hess's Law and Heats of Formation
11.6 The Kinetic and Molecular Theory of Gases
  Molecular Speed Distribution
  Gas Laws
 
Homework:
OWL 5.7c Tutor: Enthalpy of Formation 07-12-10
5.7d Homework: Enthalpy of Formation 07-12-10
11.6a Simulation: Kinetic and Molecular Theory 07-12-10
11.6e Homework: Kinetic Theory - Qualitative 07-12-10
 
Announcements:
Thursday
Jul 08
 
Lecture 18
Slides		 Lecture Material:
5.4 The First Law of Thermodynamics
  Enthalpy ... A Special Type of Heat Transfer
5.6 Determining the Heat Transfer in a Chemical Reaction
  Calorimetry
5.7 Enthalpy Calculations
  Hess's Law
     
Homework:
OWL 5.5b Tutor: Enthalpy Changes 07-09-10
5.5c Homework: Thermochemical Stoichiometry 07-09-10
5.6c Simulation: Calorimetry 07-09-10
5.6d Homework: Calorimetry 07-09-10
5.7a Simulation: Hess's Law 07-09-10
5.7b Homework: Hess's Law 07-09-10

Announcements:
1. Final Lab, Today, July 08
Wednesday
Jul 07
 
Lecture 17
Slides		 Lecture Material:
3.8 Gas-Forming Reactions
  Metal Carbonates + Weak Acid - NIE
  Types of Gas Forming Reactions
3:10 Classifying Reactions in Aqueous Solution
5.1 Energy: Some Basic Principles
5.2 Specific Heat Capacity
  Heat Transfer ... Heat Capacity
     
Homework:
OWL 3.8 Homework: Gas Forming Reactions 07-08-10
5-1d Tutor: Energy Unit Conversions 07-08-10
5-2b Simulation: Temperature Change/Heat Transfer 07-08-10
5-2c Tutor: Specific Heat Capacity 07-08-10
5-2d Tutor: Heat Equilibrium 07-08-10
5-2e Homework: Specific Heat Calculations 07-08-10
 
Announcements:
Tuesday
Jul 06
 
Lecture 16
Slides		 Lecture Material:
3.7 Acids and Bases
  Strong and Weak Acids and Bases
  Reactions of Acids and Bases
  Strong Acid + Strong Base - NIE
  Weak Acid + Strong Base - NIE
3.8 Gas-Forming Reactions
  Metal Carbonates + Strong Acid - NIE
    
Homework:
OWL 3-6e Homework: Net Ionic Equations I 07-07-10
3-6f Homework: Net Ionic Equations II 07-07-10
3.7b Simulation: Acids 07-07-10
3.7c Homework: Strong/Weak Acids 07-07-10
3.7e Homework: NIE - Acid/Base Reactions 07-07-10
 
Announcements:
1. Fifth Lab, Today, July 06
Monday
Jul 05		 No Class
Friday
Jul 02
 
Lecture 15
Slides		 Lecture Material:
9.2 Valence Bond Theory
  Hybridization
3.6 Precipitation Reactions
  Predicting the Outcome
  Solubility of Ionic Compounds in Water
  Solubility Guidelines
  Net Ionic Equations
     
Homework:
OWL 3-5e Tutor: Solubility Strong Electrolytes 07-06-10
3-5c Homework: Strong Electrolytes 07-06-10
3-6c Tutor: Precipitation Reactions 07-06-10
3-6d Tutor: Net Ionic Equations 07-06-10
3-6e Homework: Net Ionic Equations I 07-06-10
3-6f Homework: Net Ionic Equations II 07-06-10
 
Announcements:
1. No Class Monday, July 5
2. Fifth Lab, Tuesday, July 06
Thursday
Jul 01
 
Lecture 14
Slides		 Lecture Material:
8.7 Molecular Polarity
  Electronegativity Values
   Intermolecular Forces ... Class Handout ... Hydrogen Bonds
9.1 Orbitals and Theories of Chemical Bonding
9.2 Valence Bond Theory
  Hybridization
 
Homework:
OWL 8-8a Exercise: Determining Polarity of a Molecule 07-02-10
8-8b Homework: Molecular Polarity 07-02-10
9-2b Tutor: Formation of Two sp Hybrid Orbitals 07-02-10
9-2c Tutor: Formation of Three sp2 Hybrid Orbitals 07-02-10
9-2d Tutor: Formation of four sp3 Hybrid Orbitals 07-02-10
9-2e Tutor: Determining Hybrid Orbitals 07-02-10
9-2f Homework: Hybrid Orbitals 07-02-10
   
Announcements:
Wednesday
Jun 30		 Exam II - In Class
Tuesday
Jun 29		 Lecture Material:
8.6 Molecular Geometry 
  Summary ... Lone Pairs
Exam I Review
 
Homework:
  
Announcements:
1. Fourth Lab, Today, June 29
2. Exam II, Wednesday, June 30, In Class
Monday
Jun 28
 
Lecture 13
Slides		 Lecture Material:
8.6 Molecular Geometry 
  Molecular Geometry Worksheet
   Summary ... No Lone Pairs
  Summary ... Lone Pairs
 
Homework:
OWL 8-6c Tutor: Ideal Shapes 06-29-10
8-6d Tutor: Determining Molecular Shapes 06-29-10
8-6e Exercise: Determining Molecular Shapes 06-29-10
8-6f Homework: Molecular Geometry 06-29-10
 
Announcements:
Friday
Jun 25
 
Lecture 12
Slides		 Lecture Material:
8.4 Lewis Dot Structures
  Choices in Multiple Bond Formation ... Resonance
8.5 Lewis Dot Structures
  Beyond the Octet ... What to do with 'Extra' Electrons
  Some Exceptions
  Organic Molecules
8.9 Bond Properties
  Bond Order ... Bond Length
   Bond Length and Resonance
  Bond Energies
8.3 Evaluating Lewis Dot Structures
  Formal Charge
  Formal Charge Vs Oxidation Numbers
   
Homework:
OWL 8-4b Homework: Resonance Structures 06-28-10
8-5a Tutor: Exceptions to the Octet Rule 06-28-10
8-5d Homework: Interpreting Lewis Structures 06-28-10
8-9a Homework: Bond Order, Length, Strength 06-28-10
8-9c Homework: Bond Energy and Enthalpy of Reaction 06-28-10
8-3a Tutor: Formal Charge 06-28-10
8-3b Homework: Formal Charge 06-28-10
 
Announcements:
Thursday
Jun 24
 
Lecture 11
Slides		 Lecture Material:
8.2 Lewis Dot Structures
  Bond Formation Pro's and Con's
  Lewis Dot Worksheet
   Bond Pairs Vs Lone Pairs
   Dealing With Charges
  Shortage of Electrons ... Multiple Bonds
8.4 Lewis Dot Structures
  Choices in Multiple Bond Formation ... Resonance
   
Homework:
OWL 8-2b Tutor: Interpreting Lewis Structures 06-25-10
8-2c Exercise: Drawing Lewis Structures 06-25-10
8-5c Tutor: Drawing Lewis Structures 06-25-10
8-4a Tutor: Resonance Structures 06-25-10
 
Announcements:
Wednesday
Jun 23
 
Lecture 10
Slides		 Lecture Material:
7.3 Atomic Electronic Configurations
  Electronic Configuration; Orbital Box
  More Electronic Configurations ... Transition Metals
7.4 Atomic Electronic Configurations ... Ions
7.5 Periodic Trends
  Orbital Energy 

Na and Water

K and Water

Na and Water!!
Periodic Trends
  Orbital Energy            Atomic Size 
  Ionization Energy        Electron Affinity
  
Homework:
OWL 7-5c Simulation: Orbital Energies 06-24-10
7-5a Simulation: Atomic Size 06-24-10
7-5b Homework: Atomic Size 06-24-10
7-5d Simulation: Ionization Energy 06-24-10
7-5e Homework: Ionization Energy 06-24-10
7-5f Simulation: Electron Affinity 06-24-10
7-5g Simulation: Ion Charge 06-24-10
 
Announcements:
Tuesday
Jun 22
 
Lecture 9
Slides		 Lecture Material:
7.3 Atomic Electronic Configurations
  Electronic Configurations Worksheet
  Orbital Energies
  Noble Gas Configurations ... Why?
  Valence Electrons ... Group Number ... Preferred Charge
  Completed Electronic Configurations Worksheet 
  Magnetism ... Paramagnetic Vs Diamagnetic
    
Homework:
OWL 7-3d Tutor: Electron Configurations 1  06-23-10
7-3f Tutor: Electron Configurations 2 06-23-10
7-4d Tutor: Configurations and Magnetism 06-23-10
7-4e Homework: Para/Diamagnetic 06-23-10
7-3g Homework: Electron Configurations 06-23-10
7-4a Simulation: Electron Configurations of Ions 06-23-10
 
Announcements:
1. Third Lab, Today, June 22
Monday
Jun 21
 
Lecture 8
Slides		 Lecture Material:
6.6 The Shapes of Atomic Orbitals 
  Solutions of Interest to the Schrodinger Equation
 d orbitals 
   The Orbitron!
  Orbital Shapes  
  Orbital Shapes with Increasing n
7.3 Atomic Electronic Configurations
  Electronic Configurations Worksheet
  Orbital Energies
  Pauli Exclusion Principle  
  Electronic Configuration; Spectroscopic
 
Homework:
OWL 6-6a Exercise: Orbital Shapes 06-22-10
6-6b Homework: Shapes of Atomic Orbitals 06-22-10
7-3a Simulation: Electron Configurations of Atoms 06-22-10
 
Announcements:
1. Third Lab, Tuesday, June 22
Friday
Jun 18		 Exam I - In Class
Thursday
Jun 17 		Lecture Material:
6.5 Modern Quantum Theory
  Heisenberg Uncertainty Principle
  Edwin Schrodinger
Exam I Review
   
Homework:
 
Announcements:
1. Second Lab, Today, June 17
Wednesday
Jun 16
 
Lecture 7
Slides		 Lecture Material:
6.2 Energy and Photons
  Energy/Wavelength/Frequency
   Energy/Wavelength/Frequency data and Relationships
6.4 Particle-Wave Duality
  Louis de Broglie
6.5 Modern Quantum Mechanics
  Standing Wave Animation 
  Heisenberg Uncertainty Principle
  Edwin Schrodinger
 
Homework:
OWL 6-1c Tutor: Determining Frequency 06-17-10
6-1d Tutor: Determining Wavelength 06-17-10
6-2c Tutor: Energy of Light 06-17-10
6-2d Homework: Energy of Light 06-17-10
 
Announcements:
Tuesday
Jun 15
 
Lecture 6
Slides		 Lecture Material:
3.2 Balancing Chemical Equations

C60 and beyond.

Mg +CO2!
6.1 Introduction to Electromagnetic Radiation
  Wave Properties
  Electromagnetic Spectrum
Prof. David Phillips
"A Little Light Relief" 
 
Homework:
OWL 3-2c Tutor: Balancing Chemical Equations 06-16-10
3-2d Homework: Balancing Chemical Equations 06-16-10
6-1a Simulation: The Electromagnetic Spectrum 06-16-10
6-2b Simulation: Planck's Constant 06-16-10
 
Announcements:
1. Lab -- First Lab, Today, June 15
Monday
Jun 14
 
Lecture 5
Slides		 Lecture Material:
2.9 Formulas, Compounds, and the Mole
  Molar Mass (Molecular Weight)
2.10 Describing Compound Formulas
  Formula to Percent Composition
  Percent Composition to Formula
  Empirical Formula Vs Molecular Formula
   
Homework:
OWL 2-9c Tutor: Determining Molar Mass  06-15-10
2-9e Tutor: Using Molar Mass 1  06-15-10
2-9f Tutor: Using Molar Mass 2  06-15-10
2-9g Homework: Mole Calculations 1 06-15-10
2-10a Tutor: Percent Composition 06-15-10
2-10b Homework: Percent Composition 06-15-10
2-10d Tutor: Empirical Formula 06-15-10
2-10e Tutor: Molecular Formulas 06-15-10
2-10f Homework: Empirical/Molecular Formulas 06-15-10

Announcements:
Friday
Jun 11
 
Lecture 4
Slides		 Lecture Material:
2.7 Ionic Compounds
Formula and Name
  Metal + Non metal
  Metal + Polyatomic anion
  Transition Metals
2.9 Atoms, Molecules, and the Mole
  Molar Mass (Molecular Weight)
 
Homework:
OWL 2-7i Simulation: Ionic Compounds 6-14-10
2-7l Tutor: Naming Ionic Compound Formulas 6-14-10
2-7k Homework: Naming Ionic Compounds 6-14-10
2-9a Tutor: Moles and Atoms Conversions 6-14-10
2-9b Homework: Mole/Particle Conversions 6-14-10
 
Announcements:
Thursday
Jun 10
 
Lecture 3
Slides		 Lecture Material:
2.3 Isotopes
  Determining the exact mass of an isotope
2.4 Atomic Weight ... What is it?
2.5 Introduction to the Periodic Table
  Divisions in the Periodic Table
2.7 Ionic Compounds
Properties ... Coulomb's Law
  Coulomb's Law Data
   Coulomb's Law and Solubility
 
Homework:
OWL 2-4b Homework: Atomic Mass 6-11-10
2-5a Exercise: Periodic Table Organization 6-11-10
2-5b Homework: The Periodic Table 6-11-10
2-7m Simulation: Coulomb's Law 6-11-10

Announcements:
Wednesday
Jun 09
 
Lecture 2
Slides		 Lecture Material:
R.3 Mathematics of Chemistry: 
Dimensional Analysis
Scientific Notation
Significant Figures
     How Important Are Units?
2.7 Ionic Compounds
Nomenclature  ... Some Memorization 
2.1 Atomic Structure
2.2 Atomic Number and Atomic Mass
2.3 Isotopes
  Determining the exact mass of an isotope
 
Homework:
OWL R-3h Tutor: Unit Conversion 6-10-10
R-3a Tutor: Scientific Notation 1 6-10-10
R-3b Tutor: Scientific Notation 2 6-10-10
R-3c Tutor: Scientific Notation 3 6-10-10
R-3d Homework: Scientific Notation 6-10-10
2-7c Tutor: Ions, Predicting Charge 6-10-10
2-7g Tutor: Polyatomic Ions 6-10-10
2-2b Tutor: Atomic Composition 6-10-10
2-2c Homework: Atomic Composition 6-10-10
 
Announcements:
1. Daily Quizzes -- Start today.
Tuesday
Jun 08
 
Lecture 1
Slides		 Lecture Material:
Course Policy and Expectations!
  Lab Announcements
The Computer Resource Center
  Introduction to Owl
A Small Tour of Integrated Sciences Building
R.3 Mathematics of Chemistry: 
Dimensional Analysis
 
Homework:
OWL Intro to Owl Navigation, Messages, and Browsers 6-09-10
Intro to Owl Question Types in OWL 6-09-10
Intro to Owl Formulas, Scientific Notation, and Tables 6-09-10
Math Exponents 6-09-10
Math Basic Algebra 6-09-10
R-3e Homework: Significant Figures 6-09-10

Announcements: