Chem 111, Summer 2008

Instructor:

Required Materials:

Tom Whelan
Gsmn 53, 545-6092
whelan@chem.umass.edu

Textbook:
Chemistry & Chemical Reactivity, 6th Edition.
Kotz, Treichel & Weaver.

Class Meets: MTuWThF 9:30-11:00

Class Location: Gsmn 64

Chemistry Resource Center

Safety Glasses:
American Optical Co. No. 484A.

Scientific Calculator

Amanda Meier
aameier@chem.umass.edu

Ayga Frimpong
afrimpong@chem.umass.edu

Chemistry 111 Summer 2008

Syllabus Summary:

Grading

3	Exams	70%	`Highest Exam Score 26%; Lowest 20%; Other 24%`
	Quizzes	10%	`No make-up Quizzes given.`
	Laboratory	20%

Exam Policies:
You must have a passing exam average in order to pass the course.
Lab Policies:
Lab Meets Tuesday/Thursday, 1:30-4:30, Gsmn 57.
You must complete all of the laboratory experiments to pass the course.
Academic Honesty:
You will abide by the academic honesty policy of the campus. I expect you to do your own work on exams and labs. You mush flush all calculator memories of any chemistry information before coming to an exam. You MAY NOT bring any additional materials to exams other than a pencil, calculator, and your brain. I take honesty very seriously.
Grade Cutoff's:
>90's A. <55 F
The other grade cutoff's will be determined at the end of the semester. However if you want to be assured of a B you should be in the 80's and 70's for a C.
Exam Dates:

Old Exams

2007

2006

Date

Daily Schedule ... Updated Monday, July 14 :- 12:58 PM

Thursday
Jul 10

Exam III

Wednesday
Jul 09

Lecture 25

Lecture Material:

Exam III Review

Homework:

Announcements:

Exam III, Thursday July 10th ... In Class ... ~3/4 Questions from the following Lab Owls:- LO-3.3, LO-4.2, LO-4.5, LO-5.1, LO-5.5

Tuesday
Jul 08

Lecture 24

Lecture Material:

	12.6		The Kinetic and Molecular Theory of Gases
	4.4		Stoichiometry Review Limiting Reagents.

Homework:

OWL

Lab

111 TA Evaluation

07-09-08

Announcements:

Last Lab, Today, 1:30-4:30, Gsmn 57

Monday
Jul 07

Lecture 23

Lecture Material:

	6.2		Determining the Heat Transfer in a Chemical Reaction Calorimetry ... Phase Change
	12.6		The Kinetic and Molecular Theory of Gases

Homework:

OWL	Ch 6-6b	Tutor: Calculating Enthalpy Change	07-08-08
	Ch 6c	End of Chapter - Homework Tutors	07-08-08
	Ch 6-3a	Tutor: Phase Changes	07-08-08
	Ch 6b	End of Chapter - Homework Tutors	07-08-08
	Ch 12-5a	Simulation: Kinetic and Molecular Theory	07-08-08

Announcements:

Friday
Jul 04

No Class

Thursday
Jul 03

Lecture 22

Lecture Material:

	6.6		Determining the Heat Transfer in a Chemical Reaction Calorimetry ... No Phase Change
	6.7		Hess's Law
	6.8		Hess's Law and Heats of Formation
			Quiz 16

Homework:

	OWL		Ch 6-5a		Tutor: Calorimetry		07-07-08
			Ch 6a		End of Chapter - Homework Tutors		07-07-08

Announcements:

Wednesday
Jul 02

Lecture 21

Lecture Material:

	6.2		First Law of Thermodynamics Heat Transfer ... Heat Capacity
	6.5		Enthalpy ... A Special Type of Heat Transfer
	6.6		Determining the Heat Transfer in a Chemical Reaction Calorimetry ... No Phase Change
			Quiz 15

Homework:

OWL	Ch 6-2a	Tutor: Specific Heat Capacity	07-03-08
	Ch 6-2b	Tutor: Heat Equilibrium	07-03-08
	Ch 6-3b	Tutor: Enthalpy Changes	07-03-08

Announcements:

Tuesday
Jul 01

Lecture 20

Lecture Material:

	5.4		Acid/Base Reactions
	5.5		Gas Forming Reactions
	5.6		Classifying Reactions in Aqueous Solution
	6.1		Forms of Energy
			Quiz 14

Homework:

OWL	Ch 5-5a	Simulation: Acids	07-02-08
	Ch 5-7a	Tutor: Recognizing Reactions	07-02-08
	Ch 5	End of Chapter - Homework Tutors	07-02-08
	Ch 6-1a	Tutor: Energy Unit Conversions	07-02-08
	Ch 6-1b	Simulation: Temperature and Heat Transfer	07-02-08

Announcements:

Lab 5 -- Today, July 01, 1:30-4:30, Gsmn 57

Monday
Jun 30

Lecture 19

Lecture Material:

	5.1		Properties of Aqueous Solutions Predicting Solubility Solubility Guidelines
	5.2		Precipitation Reactions Net Ionic Equations
			Quiz 13

Homework:

OWL	Ch 5-1c	Tutor: Solubility Strong Electrolytes	07-01-08
	Ch 5-1b	Simulation: Solubility	07-01-08
	Ch 5-3b	Tutor: Precipitation Reactions	07-01-08
	Ch 5-2a	Tutor: Net Ionic Equations	07-01-08

Announcements:

Friday
Jun 27

Lecture 18

Lecture Material:

	10.1		Valence Bond Theory v Molecular Orbital Theory
	10.2		Valence Bond Theory Bond Formation Hybridization ... Sigma Bonds ... Methane Hybridization ... Multiple Bonds ... Ethene Pi Molecular Orbitals In Ethene Seeing is believing!!

Homework:

OWL	Ch 10-1	Tutor: Sigma Bonding	06-30-08
	Ch 10-2a	Tutor: Determining Hybrid Orbitals	06-30-08
	Ch 10-2e	Tutor: Hybridization 1	06-30-08
	Ch 10-2f	Tutor: Hybridization 2	06-30-08
	Ch 10-3a	Tutor: Pi Bonding	06-30-08
	Ch 10	End of Chapter - Homework Tutors	06-30-08

Announcements:

Thursday
Jun 26

Exam II

Wednesday
Jun 25

Lecture 17

Lecture Material:

Exam II Review

Homework:

Announcements:

Exam II -- Thursday, June 26, In Class.

Tuesday
Jun 24

Lecture 16

Lecture Material:

	9.7		Molecular Geometry Some Organic Molecules Geometry Worksheet -- Thus Far
	9.9		Molecular Polarity Electronegativity Values Intermolecular Forces ... Class Handout ... Hydrogen Bonds
			Quiz 12

Homework:

	OWL		Ch 9-8a		Exercise: Determining Polarity		06-25-08
			Ch 9d		End of Chapter - Homework Tutors		06-25-08

Announcements:

Lab 4 -- Today, Jun 24, 1:30-4:30, Gsmn 57

Monday
Jun 23

Lecture 15

Lecture Material:

	9.7		Molecular Geometry Molecular Geometry Worksheet Summary ... No Lone Pairs Summary ... Lone Pairs
			Quiz 11

Homework:

OWL	Ch 9-4a	Tutor: Ideal Shapes	06-24-08
	Ch 9-4c	Exercise: Determining Molecular Shapes	06-24-08
	Ch 9-4b1	Tutor: Determining Molecular Shapes	06-24-08
	Ch 9-4b2	Tutor: Determining Molecular Shapes	06-24-08
	Ch 9c	End of Chapter - Homework Tutors	06-24-08

Announcements:

Friday
Jun 20

Lecture 14

Lecture Material:

	9.10		Bond Properties Bond Order ... Bond Length Bond Length and Resonance Bond Energies
	9.8		Evaluating Lewis Dot Structures Formal Charge Formal Charge Vs Oxidation Numbers
	9.7		Molecular Geometry Molecular Geometry Worksheet Summary ... No Lone Pairs Summary ... Lone Pairs
			Quiz 10

Homework:

	OWL		Ch 9-6a		Tutor: Formal Charge		06-23-08
			Ch 9b		End of Chapter - Homework Tutors		06-23-08

Announcements:

Thursday
Jun 19

Lecture 13

Lecture Material:

	9.4-9.6		Lewis Dot Structures Lewis Dot Worksheet Choices in Multiple Bond Formation ... Resonance Beyond the Octet ... What to do with 'Extra' Electrons Some Exceptions and Some Organic Molecules
			Quiz 9

Homework:

OWL	Ch 9-2a	Tutor: Resonance Structures	06-20-08
	Ch 9-3a	Tutor: Electron Deficient Compounds	06-20-08
	Ch 9a	End of Chapter - Homework Tutors	06-20-08

Announcements:

Wednesday
Jun 18

Lecture 12

Lecture Material:

	9.4-9.6		Lewis Dot Structures Bond Formation Pro's and Con's Lewis Dot Worksheet Bond Pairs Vs Lone Pairs Dealing With Charges Shortage of Electrons ... Multiple Bonds
			Quiz 8

Homework:

OWL	Ch 9-1a	Tutor: Interpreting Lewis Structures	06-19-08
	Ch 9-1c	Exercise: Drawing Lewis Structures	06-19-08
	Ch 9-1b	Tutor: Drawing Lewis Structures	06-19-08

Announcements:

Tuesday
Jun 17

Lecture 11

Lecture Material:

8.4	Atomic Electronic Configurations Completed Electronic Configurations Worksheet More Electronic Configurations ... Transition Metals
8.5	Atomic Electronic Configurations ... Ions
8.6	Periodic Trends Orbital Energy Atomic Size Ionization Energy Electron Affinity Metallic Character

	Na and Water	K and Water	Na and Water!!
	Quiz 7

Homework:

OWL	Ch 8-6b	Simulation: Configurations of Ions	06-18-08
	Ch 8-6a	Tutor: Electron Configurations of Ions	06-18-08
	Ch 8a	End of Chapter - Homework Tutors	06-18-08
	Ch 8-8a	Simulation: Orbital Energies	06-18-08
	Ch 8-8b	Simulation: Atomic Size	06-18-08
	Ch 8-9a	Simulation: Ionization Energy	06-18-08
	Ch 8-11	Simulation: Electron Affinity	06-18-08
	Ch 8-12a	Simulation: Ion Charge	06-18-08
	Ch 8-12b	Simulation: Ion Size	06-18-08
	Ch 8b	End of Chapter - Homework Tutors	06-18-08

Announcements:

Third Lab Session -- Today, June 17, 1:30-4:30, Gsmn 57

Monday
Jun 16

Lecture 10

Lecture Material:

8.4

Atomic Electronic Configurations

Electronic Configurations Worksheet

Orbital Energies ... Why Are the Noble Gases 'Inert'

Pauli Exclusion Principle

Electronic Configuration; Spectroscopic, Noble Gas

Electronic Configuration; Orbital Box

Magnetism ... Paramagnetic V Diamagnetic

Valence Electrons ... Group Number ... Preferred Charge

Homework:

OWL	Ch 8-4a	Simulation: Electron Configurations	06-17-08
	Ch 8-4b	Tutor: Electron Configurations 1	06-17-08
	Ch 8-5a	Tutor: Electron Configurations 2	06-17-08
	Ch 8-7a	Tutor: Configurations and Magnetism	06-17-08

Announcements:

Friday
Jun 13

Exam I

Thursday
Jun 12

Lecture 9

Lecture Material:

Exam I Review

Homework:

Announcements:

Exam I -- Friday, June 13, In Class.

Wednesday
Jun 11

Lecture 8

Lecture Material:

	7.5		Modern Quantum Theory Heisenberg Uncertainty Principle Edwin Schrodinger
	7.6		The Shapes of Atomic Orbitals Solutions of Interest to the Schrodinger Equation The Orbitron! Orbital Shapes Orbital Shapes with Increasing n
			Quiz 6

Homework:

	OWL		Ch 7-8a		Exercise: Shapes of Atomic Orbitals		06-12-08
			Ch 7b		End of Chapter - Homework Tutors		06-12-08

Announcements:

Tuesday
Jun 10

Lecture 7

Lecture Material:

	7.1		Standing Waves (Fixed Start and End) Standing Wave Animation
	7.4		The Wave Properties of the Electron
	7.5		Modern Quantum Theory Heisenberg Uncertainty Principle Edwin Schrodinger
			Quiz 5

Homework:

OWL	Ch 7-2a	Tutor: Determining Frequency	06-11-08
	Ch 7-2b	Tutor: Determining Wavelength	06-11-08
	Ch 7-3b	Tutor: Energy of Light	06-11-08
	Ch 7a	End of Chapter - Homework Tutors	06-11-08

Announcements:

First Lab Session -- Today, June 10, 1:30-4:30, Gsmn 57

Monday
Jun 09

Lecture 6

Lecture Material:

	4.2		Balancing Chemical Equations
	7.1		Introduction to Electromagnetic Radiation Wave Properties Electromagnetic Spectrum Energy/Wavelength/Frequency
			Prof. David Phillips "A Little Light Relief"
			Quiz 4

Homework:

OWL	Ch 4-1b	Tutor: Balancing Chemical Equations	06-10-08
	Ch 4	End of Chapter - Homework Tutors	06-10-08
	Ch 7-1a	Simulation: The Electromagnetic Spectrum	06-10-08
	Ch 7-3a	Simulation: Planck's Constant	06-10-08

Announcements:

Friday
Jun 06

Lecture 5

Lecture Material:

Homework:

OWL	Ch 3-12a	Tutor: Percent Composition	06-09-08
	Ch 3-12b	Tutor: Empirical Formula	06-09-08
	Ch 3-12d	Tutor: Molecular Formulas	06-09-08
	Ch 3b	End of Chapter - Homework Tutors	06-09-08

Announcements:

Thursday
Jun 05

Lecture 4

Lecture Material:

	3.3		Ionic Compounds Formula and Name ... Ionic Compounds Metal + Non metal Metal + Polyatomic anion Transition Metals
	3.5		Formulas, Compounds, and the Mole Molar Mass (Molecular Weight)
			Quiz 2

Homework:

OWL	Ch 3-5a	Simulation: Ionic Compounds	06-06-08
	Ch 3-6b	Tutor: Naming Ionic Compound Formulas	06-06-08
	Ch 3a	End of Chapter - Homework Tutors	06-06-08
	Ch 3-10b	Tutor: Determining Molar Mass	06-06-08
	Ch 3-11a	Tutor: Using Molar Mass 1	06-06-08
	Ch 3-11b	Tutor: Using Molar Mass 2	06-06-08

Announcements:

Wednesday
Jun 04

Lecture 3

Lecture Material:

	2.6		Introduction to the Periodic Table Divisions in the Periodic Table
	3.3		Ionic Compounds ... Coulomb's Law Coulomb's Law Data Coulomb's Law and Solubility
			Quiz 1

Homework:

OWL	Ch 2-4a	Exercise: Periodic Table Organization	06-05-08
	Ch 2	End of Chapter - Homework Tutors	06-05-08
	Ch 3-9a	Simulation: Coulomb's Law	06-05-08

Announcements:

Tuesday
Jun 03

Lecture 2

Lecture Material:

	3.3		Ionic Nomenclature ... The Basics ... Some Memorization
	2.2		Composition of The Atom
	2.3		Isotopes Determining the exact mass of an isotope
	2.4		Atomic Weight ... What is it?

Homework:

OWL	Ch 1-7b	Tutor: Unit Conversion	06-04-08
	Ch 1-5a	Tutor: Scientific Notation 1	06-04-08
	Ch 1-5b	Tutor: Scientific Notation 2	06-04-08
	Ch 1-5c	Tutor: Scientific Notation 3	06-04-08
	Ch 1	End of Chapter - Homework Tutors	06-04-08
	Ch 3-3b	Tutor: Ions, Predicting Charge	06-04-08
	Ch 3-4c	Tutor: Polyatomic Ions	06-04-08
	Ch 2-1b	Tutor: Atomic Composition	06-04-08
	Ch 2-1c	Tutor: Average Atomic Mass	06-04-08

Announcements:

Daily Quizzes -- Start tomorrow, June 4.

Monday
Jun 02

Lecture 1

Lecture Material:

			Course Policy and Expectations! Lab Announcements The Chemistry Resource Center Introduction to Owl A Small Tour of Gsmn
	1.7		Mathematics of Chemistry: Dimensional Analysis How Important Are Units?

Homework:

OWL	Ch 0-1a	Intro to OWL: Start Here	06-03-08
	Ch 0-1b	Intro to OWL: Question Types in OWL	06-03-08
	Ch 0-1c	Intro to OWL: Important things to learn	06-03-08
	Ch 0-2	Math: Exponents	06-03-08
	Ch 0-3	Math: Basic Algebra	06-03-08

Announcements: