Chem 110

Fall 2009

Instructors:



Tom Whelan
ISB 241E, 545-6092
 whelan@chem.umass.edu
Office Hours
Friday: 2:30-4:30, ISB 155



Max Lein
mlein@chem.umass.edu 
 CRC: Wed 8-10pm

 

  



Ebru Kizilay
 ekizilay@chem.umass.edu
CRC: Fri 2-4pm
     


Tsung-Yi Lin
 tlin@chem.umass.edu
CRC: Tue 12-1pm

 

  



Christopher Ferreira
 c_j_ferreira@yahoo.com
CRC: Tue 2-4pm
Required Materials:  
INTRODUCTION TO
General, Organic, and
Biochemistry

EIGHT EDITION
Bettelheim . Brown . Campbell . Farrell 		 
  1. Class Meets:  TuTh 1:00-2:15, 
  2. Class Location:  ISB 135
  3. Exam Dates: 10-6,  11-5,  12-8,  TBA
  4. Campus Map
  5. PRS - Personal Response System
  6. Scientific Calculator
    (Easy to use and inexpensive)
Syllabus Summary:
  1. Grading
    3 In Class Exams + Final Exam 70%                                                 
    (Highest Exam Score of All Exams 20%; Lowest 14%; Other 2, 18% each)
    PRS + Owl 10%
    Laboratory 20%
  2. Exam Dates:
    Final Friday December 18 Marc 131 4:00-6:00
  3. Past Exams
    2009 Exam I - Blank Exam II - Blank Exam III - Blank
    Exam I - Key Exam II - Key Exam III - Key
    2007 Exam I - Blank Exam II - Blank Exam III - Blank
    Exam I - Key Exam II - Key Exam III - Key
    2006 Exam I - Blank Exam II - Blank Exam III - Blank
    Exam I - Key Exam II - Key Exam III - Key
  4. Exam Policies:
    You must have a passing exam average  in order to pass the course. 
  5. Lab Policies:
    You must complete all of the laboratory experiments to pass the course.
  6. Academic Honesty:
    You will abide by the academic honesty policy of the campus.  I expect you to do your own work on exams and labs.  You mush flush all calculator memories of any chemistry information before coming to an exam.  You MAY NOT bring any additional materials to exams other than a pencil, calculator, and your brain.  I take honesty very seriously.  
  7. Grade Cutoff's:
    >90  A.                <55 F
    The other grade cutoff's will be determined at the end of the semester.  However if you want to be assured of a B you should be in the 80's and 70's for a C.  Performance on the final will determine borderline grades.
Date Daily Schedule ... Updated Sunday, November 09 :- 01:24 PM
Friday
Dec 18		 Final Exam - Marcus 131 - 4:00-6:00pm
Thursday
Dec 10		 Lecture Material:
Exam III -- Stats and Answer Key
  
Homework:

Announcements:
2. Final Friday, December 18, Marcus 131, 4-6pm
 -- Review Session, Sunday Dec 13, ISB 135, 4-6pm
Tuesday
Dec 08		 Exam III - ISB 135 - 12:45-2:15pm
Thursday
Dec 03
 
Lecture 21
Slides		 Lecture Material:
9.11 How Do We Calculate the pH of a Buffer
5.5 Stoichiometry
  Lab Owls -- Review
  
Homework:
Owl Ch 9.11d Homework  --  pH of Buffer Solutions 12-05-09
 
Announcements:
1. Exam III Tuesday, December 8, In Class.
 -- 3 or 4 questions will be taken from Lab Owls 4 and 5
 -- Review Session, Sunday Dec 6, ISB 135, 4-6pm
Tuesday
Dec 01
 
Lecture 20
Slides		 Lecture Material:
9.10 What Are Buffers?
  B:  Buffer pH
  C:  Buffer Capacity
  D:  Blood Buffers and Metabolic Acidosis
9.11 How Do We Calculate the pH of a Buffer
  
Homework:
Owl Ch 9.11e Homework  --  Buffer + Acid/Base Qualitative 12-03-09
 
Announcements:
Thursday
Nov 26		 Thanksgiving
Tuesday
Nov 24
 
Lecture 19
Slides		 Lecture Material:
9.3 What are Conjugate Acid-Base Pairs?
9.10 What Are Buffers?
  A:  How Do They Work
  B:  Buffer pH
  
Homework:
Owl Ch 9.3a Exercise  --  Bronsted Acid-Base Reactions 12-01-09
Ch 9.3b Homework  --  Conjugate Acid-Base Pairs 12-01-09
Ch 9.10a Simulation  --  Buffer Solutions 12-01-09
Ch 9.10b Tutor  --  Identifying Buffer Solutions 12-01-09
Ch 9.10c Homework  --  Buffer Solutions 12-01-09
Ch 9.11a Simulation  -- pH of Buffer Solutions 12-01-09
Ch 9.11b Simulation  -- Preparation of Buffer Solutions 12-01-09
 
Announcements:
Thursday
Nov 19
 
Lecture 18
Slides		 Lecture Material:
9.7 Acid/Base Properties of Water
9.8 What Are pH and pOH
  The pH Scale
  pH and Soil
  
Homework:
Owl Ch 9.8b Homework  --  pH and pOH 11-24-09
Ch 9.8c Tutor  --  The pH Scale 11-24-09
Ch 9.8d Homework  --  pH and pOH Calculations 11-24-09
Ch 9.8e Tutor  --  pH Strong Acids 11-24-09
Ch 9.8f Tutor  --  pH Strong Bases 11-24-09
   
Announcements:
Tuesday
Nov 17
 
Lecture 17
Slides		 Lecture Material:
9.2 Defining the Strength of Acids and Bases?
  Weak Acid Equilibrium Constants -- Ka
9.5 How Do We Use Acid Ionization Constants?
  pKa for Some Amino Acids
9.7 Acid/Base Properties of Water
  
Homework:
Owl Ch 9.2b Homework  --  Acid and Base Strength 11-19-09
Ch 9.5b Homework  -- Acid Ionization Constants 11-19-09
Ch 9.7 Homework  -- Self-ionization of Water 11-19-09
Ch 9.8a Simulation  --  The pH Scale 11-19-09
   
Announcements:
Thursday
Nov 12
 
Lecture 16
Slides		 Lecture Material:
8.8 Le Chatelier's Principle
  D:  Change in Pressure
Le Chatelier's and Hemoglobin
9.1 What Are Acids and Bases?
   
Homework:
Owl Ch 9.1b Homework  --  Acids and Bases 11-17-09
Ch 9.2a Simulation  --  Acids 11-17-08
Ch 9.5a Homework  --  How To Use Logs and Antilogs 11-17-08
   
Announcements:
Tuesday
Nov 10
 
Lecture 15
Slides		 Lecture Material:
8.8 Le Chatelier's Principle
  A:  Addition of a Reaction Component
          Add Reactant -- Add Product
  B:  Removal of a Reaction Component
          Remove Reactant -- Remove Product
  C:  Change in Temperature
  D:  Change in Pressure
Le Chatelier's and Hemoglobin
  
Homework:
Owl Ch 8.8a Homework  --  Le Chatelier's: Concentration/Temp. 11-12-09
Ch 8.8b Homework  --  Le Chatelier's: Pressure/General 11-12-09
  
Announcements:
Thursday
Nov 05		 Exam II - ISB 135 - 12:45-2:15pm
Tuesday
Nov 03		 Lecture Material:
8.8 Le Chatelier's Principle
Exam II Review
  
Homework:
 
Announcements:
1. Exam II Thursday, November 5, In Class.
Thursday
Oct 29
 
Lecture 14
Slides		 Lecture Material:
8.5 What Does It Mean to Say That a Reaction Has Reached Equilibrium
  Hemoglobin
   Equilibrium
8.6 What Is an Equilibrium Constant and How Do We Use it?
8.8 Le Chatelier's Principle
   
Homework:
Owl Ch 8.6c Tutor  --  Writing Equilibrium Expressions 11-03-09
Ch 8.6b Simulation  --  Writing Equilibrium Expressions 11-03-09
Ch 8.6d Homework  -- The Equilibrium Constant 11-03-09
Ch 8.6f Simulation  -- Meaning of the Equilibrium Constant 11-03-09
Ch 8.6g Homework  -- Significance of K 11-03-09
 
Announcements:
1. Help Session Sunday, November 01, ISB 135, 4pm
Tuesday
Oct 27
 
Lecture 13
Slides		 Lecture Material:
4.11 How Do We Determine if a Molecule is Polar
  Electronegativity Comparisons
   Some Consequences of Molecular Polarity
   Potassium Permanganate Dissolution
   Lead Poisoning
   Fabric Softener
   
Homework:
Owl Ch 4.11a Exercise  -- Determining Polarity 10-29-09
Ch 4.11b Homework  --  Polarity of Molecules 10-29-09
Ch 8.5a Simulation  -- Equilibrium State 10-29-09
Ch 8.6a Simulation  -- Equilibrium State 10-29-09
Red Assignments due prior to class.
 
Announcements:
Thursday
Oct 22
 
Lecture 12
Slides		 Lecture Material:
4.10 Molecular Geometries and Bond Angles
  Molecular Geometry Worksheet
     Morphine  ---   Taxol   ---   Caffeine 
     Tamiflu   --- Check out the Molecular Playground
 
Homework:
Owl Ch 4.10a Homework  --  Shapes of Molecules 10-27-09
Ch 4.10b Tutor  -- Ideal Repulsion Shapes 10-27-09
Ch 4.10c Tutor  --  Determining Molecular Shapes 10-27-09
Ch 4.10d Exercise  -- Determining Molecular Shapes 10-27-09
Ch 4.10e Homework  -- Predicting Shapes of Molecules 10-27-09
 
Announcements:
1. Help Session Sunday, October 25, ISB 221, 4pm
Tuesday
Oct 20
 
Lecture 11
Slides		 Lecture Material:
4.7 Drawing Lewis Structures of Covalent Compounds
  Organic Molecules
4.8 Naming Binary Covalent Molecules
4.10 Molecular Geometries and Bond Angles
  Molecular Geometry Worksheet
 
Homework:
Owl Ch 4.8a Tutor  --  Naming Covalent Compounds 10-22-09
Ch 4.8b Homework  -- Naming Covalent Compounds 10-22-09
 
Announcements:
Thursday
Oct 15
 
Lecture 10
Slides		 Lecture Material:
4.7 Drawing Lewis Structures of Covalent Compounds
  Lewis Dot Worksheet
   Shortage of Electrons ... Multiple Bonds
  Choices ... Resonance
 
Homework:
Owl Ch 4.9a Tutor  --  Resonance Structures  10-20-09
Ch 4.9b Homework  --  Resonance Structures 10-20-09
Ch 4.7g Homework  --  Drawing Lewis Structures 10-20-09
Ch 4a Tutors  --  End of Chapter Questions 10-20-09
  
Announcements:
Tuesday
Oct 13 		Academic Monday -- No Class
Thursday
Oct 08
 
Lecture 9
Slides		 Lecture Material:
4.7 What Is a Covalent Bond and How Does One Form
  Bond Formation Pro's and Con's 
4.7 Drawing Lewis Structures of Covalent Compounds
  Lewis Dot Worksheet
  Bond Pair and Lone Pair Electrons
  Dealing With Cations and Anions
  Shortage of Electrons ... Multiple Bonds
 
Homework:
Owl Ch 4.7b Tutor  --  Interpreting Lewis Structures 10-15-09
Ch 4.7d Homework  --  Interpret Lewis Structures 10-15-09
Ch 4.7e Tutor  --  Drawing Lewis Structures  10-15-09
Ch 4.7f Exercise  --  Drawing Lewis Structures  10-15-09
 
Announcements:
Tuesday
Oct 06 		Exam I - ISB 135 - 12:45-2:15pm
Thursday
Oct 01
 
Lecture 8 		Lecture Material:
2.8 What Are Periodic Properties
  Electronegativity
Exam I Review
  
Homework:
  
Announcements:
1. Exam I Tuesday, October 6, In Class.
Tuesday
Sep 29
 
Lecture 7
Slides		 Lecture Material:
2.6 How Are the Electrons in an Atom Arranged
  Electron Configurations ... Transition Metals
  Electron Configurations Worksheet-Completed
2.7 Electron Configuration and Preferred Charge
  Periodic Blocks
2.8 What Are Periodic Properties
  Brainaic Alkali Metal Movie
  Atomic Size ... Why is this?
  Ionization Energy
  Electronegativity
  
Homework:
Owl Ch 2.7 Homework   --  Configurations & The Periodic Table  10-01-09
Ch 2.8a Simulation  --  Atomic Size 10-01-09
Ch 2.8b Homework   --  Periodic Properties 10-01-09
Ch 2b Tutor  --  End of Chapter Homework Tutors 10-01-09
Ch 4.4 Homework   --  Electronegativity 10-01-09
 
Announcements:
1. Exam I Tuesday, October 6, In Class.
Thursday
Sep 24
 
Lecture 6
Slides		 Lecture Material:
2.6 How Are the Electrons in an Atom Arranged
  Shapes of Atomic Orbitals ... Atomic Orbital Worksheet
  Electron Configurations Worksheet
  Rules Governing Electron Configurations ... The Obital Stairway!!
  Electron Configurations ... Orbital Box ... Noble Gas ... Lewis Dot
  Electron Configurations ... Transition Metals
  
Homework:
Owl Ch 2.6b Simulation -- Electronic Configurations 09-29-09
Ch 2.6c Tutor -- Electronic Configurations 2 09-29-09
Ch 2.6d Homework -- Electronic Configurations of Atoms 09-29-09
 
Announcements:
Tuesday
Sep 22
 
Lecture 5
Slides		 Lecture Material:
5.4 How Do We Balance Chemical Equations

C60 and beyond.

Mg +CO2!

2.6 How Are the Electrons in an Atom Arranged
  Shapes of Atomic Orbitals ... Atomic Orbital Worksheet
  
Homework:
Owl Ch 5.4b Tutor -- Balancing Chemical Equations 09-24-09
Ch 5.4c Homework -- Balancing Chemical Equations 09-24-09
Ch 5a End of Chapter -- Homework Tutors 09-24-09
Ch 2.6a Homework: Shells Sub-shells & Orbitals 09-24-09
 
Announcements:
Thursday
Sep 17
 
Lecture 4
Slides		 Lecture Material:
4.6 How Do We Predict Formulas and Name Ionic Compounds
5.3 What Is a Mole and How Do We Use It?
  Molar Mass ... Formula Weight
  
Homework:
Owl Ch 4.6a Tutor -- Naming Ionic Compound Formulas 09-22-09
Ch 4.3b Homework -- Naming Ions 09-22-09
Ch 4.6b Homework -- Naming Ionic Compounds 09-22-09
Ch 5.3c Tutor -- Determining Molar Mass 09-22-09
Ch 5.3e Tutor -- Using Molar Mass 1 09-22-09
Ch 5.3f Tutor -- Using Molar Mass 2 09-22-09
Ch 5.3g Homework -- Mole/Mass Calculations 09-22-09
 
Announcements:
Tuesday
Sep 15
 
Lecture 3
Slides		 Lecture Material:
2.2 What Are Atoms Made Of
  Isotopes ... Determining Exact Mass
  Atomic Weight -- What is it?
2.5 What Is the Periodic Table ... How is it organized?
4.5 What is an Ionic Bond and What Holds it Together
  Coulomb's Law Data

Homework:
Owl Ch 2.4d Tutor -- Average Atomic Mass 09-17-09
Ch 2a End of Chapter -- Homework Tutors 09-17-09
Ch 2.5a Exercise -- Periodic Table Organization 09-17-09
Ch 2.2b Homework -- Names, Symbols and Formulas 09-17-09
Ch 4.1ab Simulation -- Coulomb's Law 09-17-09
Ch 4.5b Simulation -- Ionic Compounds 09-17-09
 
Announcements:
1. Labs Start this week - Odd Sections .... L01,L03,L05,L07,L09
Thursday
Sep 10
 
Lecture 2
Slides		 Lecture Material:
1.5 Factor-Label Method -- Dimensional Analysis -- Mathematics of Chemistry
4.4 How Do We Name Anions and Cations -- A Brief Early Visit!
  Some Memorization
2.2 What Are Atoms Made Of
  Three Subatomic Particles
  Mass Number/Atomic Number
 
Homework:
Owl Ch 1.5d Tutor -- Metric System Prefixes 09-15-09
Ch 1.5c Tutor -- Unit Conversions 09-15-09
Ch 1.3c Homework -- Significant Figures 09-15-09
Ch 1a End of Chapter -- Homework Tutors 09-15-09
Ch 4.2c Tutor -- Ions: Predicting Charge 09-15-09
Ch 4.3a Tutor -- Polyatomic Ions 09-15-09
Ch 2.4b Tutor -- Atomic Composition 09-15-09
 
Announcements:
Tuesday
Sep 08
 
Lecture 1
Slides		 Lecture Material:
General Course Information
  What Materials Do I Need
  Exam Dates & Grading
  Computer Resource Center
  Lab -- What/Where/When/What I Need to Know/Materials etc
  Some Fun With Balloons!
1.5 Factor-Label Method -- Dimensional Analysis -- Mathematics of Chemistry
 
Homework:
Reading Ch 1.2 What is the Scientific Method
Ch 1.3 How do Scientists Report Numbers
Ch 1.4 How do we Make Measurements
Owl Ch 0.1a Intro to OWL -- Start Here 09-10-09
Ch 0.1b Intro to OWL-- Question Types in OWL 09-10-09
Ch 0.1c Intro to OWL -- Important things to learn 09-10-09
 
Announcements: