Chem 110

Fall 2015
Instructors:
   



Tom Whelan
ISB 241E, 545-6092
 whelan@chem
Office Hours
Mon: 2:45-4:45 ISB 162  Where is ISB 162? 
Wed: 2:45-4:45 ISB 162



Aidan McKenna
amckenna@umass
CRC: Wed: 10:30-12:30

 

  



Anton El Khoury
aelkhoury@umass
CRC: Mon/Wed: 11:10-12:10



Artur Wysoczanski
awysocza@umass
CRC: Wed: 1:00-3:00

 

  



Jeff Raymond
jjraymond@umass
CRC: Wed: 2:30-4:30



Puneet Singh
pksingh@umass
CRC: Mon: 10:15-12:15

 

  



Sarmad Al-Khamees
salkhamees@umass
CRC: Mon/Fri: 11:00-12:00



Soo Lim Park
soolimpark@umass
CRC: Mon: 1:45-2:45
CRC: Tue: 11:30-12:30

 

  



Taeyil Son
tson@umass
CRC: Mon/Wed: 10:15-11:15

Recommended Textbook:  
INTRODUCTION TO
General, Organic, and
Biochemistry

Ninth EDITION
Bettelheim . Brown . Campbell . Farrell 		 
  1. Class Meets:  TuTh 1:00-2:15, 
  2. Class Location:  ISB 135
  3. Exam Dates: Oct 6, Nov 10, Dec 8, TBA
  4. Campus Map
  5. iClicker 2
  6. Scientific Calculator
    (Easy to use and inexpensive)
Acknowledgement
Prof. William Vining at SUNY Oneonta.
Many of his interactive modules I have links to on this web page.  To see a host more of these and find out what Bill was up to in the picture on the left ... just click on the image! 
Syllabus Summary:
  1. General:
    This course satisfies the physical science General Education requirement (PS).  The aim of GenEd is to help students develop mature, broad, transferable skill sets that are not limited to one particular discipline or profession.  The PS GenEd courses grow analytical reasoning, critical thinking, complex problem solving, mathematical acumen, logical argument, and other life skills.  In this class we work on these skills using the language and concepts of chemistry, but the skills are transferable to any field.
  2. Grading
    3 In Class Exams + Final Exam 70%                                                 
    (Highest Exam Score of All Exams 20%; Lowest 14%; Other 2, 18% each)
    PRS + Owl 10%
    Laboratory 20%
  3. Exam Dates:
    Exam I Tuesday October 6 ISB 135 1:00-2:15
    Exam II Tuesday November 10 ISB 135 1:00-2:15
    Exam III Tuesday December 8 ISB 135 1:00-2:15
    Final Friday December 18 Gsmn 64 10:30-12:30
  4. Past Exams
    2015 Exam I - Blank Exam II - Blank Exam III - Blank
    Exam I - Key Exam II - Key Exam III - Key
    2014 Exam I - Blank Exam II - Blank Exam III - Blank
    Exam I - Key Exam II - Key Exam III - Key
    2013 Exam I - Blank Exam II - Blank Exam III - Blank
    Exam I - Key Exam II - Key Exam III - Key
    2012 Exam I - Blank Exam II - Blank Exam III - Blank
    Exam I - Key Exam II - Key Exam III - Key
  5. Exam Policies:
    You must have a passing exam average in order to pass the course -- Failing two of the exams constitutes a failing exam average. 
  6. Lab Policies:
    You must complete all of the laboratory experiments to pass the course.
  7. Academic Honesty:
    You will abide by the academic honesty policy of the campus.  I expect you to do your own work on exams and labs.  You mush flush all calculator memories of any chemistry information before coming to an exam.  You MAY NOT bring any additional materials to exams other than a pencil, calculator, and your brain.  I take honesty very seriously.  
  8. Grade Cutoff's:
    >90  A.                <55 F
    The other grade cutoff's will be determined at the end of the semester.  However if you want to be assured of a B you should be in the 80's and 70's for a C.  Performance on the final will determine borderline grades.
Date Daily Schedule ... Updated Friday, December 11 :- 02:48 PM
Friday
Dec 18		 Final Exam - Gsmn 64 - 10:30-12:30pm
Thursday
Dec 10
 
Lecture 23		 Lecture Material:
4.5 Stoichiometry
  Lab Owls -- A Review
Course Wrap-Up
  
Homework:
 
 Announcements:
2. Final Exam   Friday, December 18, 10:30-12:30, Gsmn 64
Tuesday
Dec 08		 Exam III - ISB 135 - 1:00-2:15pm
Thursday
Dec 03
 
Lecture 22
Slides		 Lecture Material:
9.3 What Happens When a Nucleus Emits Radioactivity?
   B:  Beta Emission
  C:  Alpha Emission -- Alexander Litvinenko(2006)
  D:  Positron Emission -- PET Imaging
  F:  Electron Capture
4.5 Stoichiometry
  Lab Owls -- Review
  
Homework:
Owl 9.3b Homework    Alpha Decay 12-07-15
9.3c Homework    Beta Decay 12-07-15
9.3d Homework    Positron Emission and Electron Capture 12-07-15
9.3e Homework    Identify Nuclear Decay 12-07-15
 
Announcements:
1. Lab   Final Lab - Saturday, December 5, 1:00-4:00pm
There is no prelab quiz associated with this lab.  Instead a TA
Evaluation Survey can be found in your CLASS OWLS.
Completing this by Friday December 11th is the equivalent of
a perfect pre-lab quiz. 
2. Exam III   Tuesday, December 8th, In Class.
Three/Four questions will be taken from:
Lab Owls 3, 4, and 5.
Tuesday
Dec 01
 
Lecture 21
Slides		 Lecture Material:
8.11 How Do We Calculate the pH of a Buffer
9.3 What Happens When a Nucleus Emits Radioactivity?
   B:  Beta Emission
  C:  Alpha Emission -- Alexander Litvinenko(2006)
  
Homework:
Owl 8.11d Homework    pH of Buffer Solutions 12-04-15
9.3a Tutor    Balancing Nuclear Reaction Equations 12-04-15
 
Announcements:
Thursday
Nov 26		 Thanksgiving - No Class
Tuesday
Nov 24
 
Lecture 20
Slides		 Lecture Material:
8.10 What Are Buffers?
  Preparing Buffer Solutions
   C:  Buffer Capacity
  D:  Blood Buffers and Metabolic Acidosis
  
Homework:
Owl 8.10c Homework    Buffer Solutions Identify Buffer 12-01-15
8.10d Homework   Write Equation for Buffer Action 12-01-15
8.10e Homework   Buffer Solutions - Buffer Capacity 12-01-15
8.11a Simulation   pH of Buffer Solutions 12-01-15
8.11b Simulation   Preparation of Buffer Solutions 12-01-15
 
Announcements:
Thursday
Nov 19
 
Lecture 19
Slides		 Lecture Material:
8.3 What are Conjugate Acid-Base Pairs?
  Anions ... Bases??
8.10 What Are Buffers?
  A:  How Do They Work
  B:  Buffer pH
  
Homework:
Owl 8.3a Exercise    Bronsted Acid-Base Reactions 11-24-15
8.3b Homework    Bronsted Acid Base Pairs 11-24-15
8.3c Homework    Conjugate Acid-Base Pairs 11-24-15
8.10a Simulation   Buffer Solutions 11-24-15
8.10b Tutor   Identifying Buffer Solutions 11-24-15
 
Announcements:
Tuesday
Nov 17
 
Lecture 18
Slides		 Lecture Material:
8.8 What Are pH and pOH
  The pH Scale
  pH and Soil
8.3 What are Conjugate Acid-Base Pairs?
  Anions ... Bases??
8.10 What Are Buffers?
  A:  How Do They Work
 
Homework:
Owl 8.8b Homework    pH and pOH Calculations 11-20-15
8.8c Homework    pH and pOH Ordering Acidity 11-20-15
8.8d Tutor    The pH Scale 11-20-15
8.8e Homework    Concentration to pH and pOH Calculations 11-20-15
8.8f Homework    pH and pOH to Concentration Calculations 11-20-15
8.8g Tutor    pH Strong Bases 11-20-15
 
Announcements:
Thursday
Nov 12
 
Lecture 17
Slides		 Lecture Material:
8.1 What Are Acids and Bases?
  Acid Ionization
8.2 Defining the Strength of Acids and Bases?
  Weak Acid Equilibrium Constants -- Ka
8.5 How Do We Use Acid Ionization Constants?
  pKa for Some Amino Acids
8.7 Acid/Base Properties of Water
8.8 What Are pH and pOH
  The pH Scale
 
 Homework:
Owl 8.1b Homework    Acids in Water 11-17-15
8.1c Homework   Bases in Water 11-17-15
8.2a Simulation   Acids 11-17-15
8.2b Homework   Acid and Base Strength 11-17-15
8.5a Homework   How To Use Logs and Antilogs 11-17-15
8.7a Homework   Self-ionization of Water 11-17-15
8.8a Simulation   The pH Scale 11-17-15
 
 Announcements:
1. Lab   Fifth Lab - Saturday, November 14, 1:00-4:00pm
Tuesday
Nov 10		 Exam II - ISB 135 - 1:00-2:15pm
Thursday
Nov 05
 
Lecture 16
Slides		 Lecture Material:
7.7 Le Chatelier's Principle
  D:  Change in Pressure
Le Chatelier's and Hemoglobin
 
Homework:
Owl 7.7c Homework    Le Chatelier's: Temperature 11-09-15
7.7d Homework    Le Chatelier's: Pressure 11-09-15
7.7e Homework    Le Chatelier's: Multiple Effects 11-09-15
 
Announcements:
1. Exam II   Tuesday, November 10, 1:00-2:15, In Class
Tuesday
Nov 03
 
Lecture 15
Slides		 Lecture Material:
7.7 Le Chatelier's Principle
  A:  Addition of a Reaction Component
          Add Reactant -- Add Product
  B:  Removal of a Reaction Component
          Remove Reactant -- Remove Product
  C:  Change in Temperature
  
Homework:
Owl 7.6i Simulation   The Meaning of K 11-06-15
7.6j Homework   Significance of K 11-06-15
7.7a Homework   Le Chatelier's: Concentration. 11-06-15
7.7b Homework    Le Chatelier's: Temperature 11-06-15
 
Announcements:
Thursday
Oct 29
 
Lecture 14
Slides		 Lecture Material:
7.5 What Does It Mean to Say That a Reaction Has Reached Equilibrium
  Hemoglobin
   Equilibrium
7.6 What Is an Equilibrium Constant and How Do We Use it?
  Writing Equilibrium Expressions
  Meaning and Significance of K
   
Homework:
Owl 7.6c Tutor   Writing Equilibrium Expressions 11-03-15
7.6d Homework   The Equilibrium Constant 11-03-15
7.6e Homework   Equilibrium Relationships - Gas Phase 11-03-15
7.6f Homework   Equilibrium Relationships - Aqueous 11-03-15
7.6h Homework   K Calculations - Aqueous 11-03-15
  
 Announcements:
1. Lab   Fourth Lab - Saturday, October 31, 1:00-4:00pm
Tuesday
Oct 27
 
Lecture 13
Slides		 Lecture Material:
3.11 How Do We Determine if a Molecule is Polar
  Electronegativity Comparisons
   Some Consequences of Molecular Polarity
   Potassium Permanganate Dissolution
   Lead Poisoning
   Fabric Softener
   
Homework:
Owl 3.11b Homework   Polarity from Molecular Model 10-30-15
3.11c Homework   Polarity from Formula 10-30-15
 
Announcements:
Thursday
Oct 22
 
Lecture 12
Slides		 Lecture Material:
3.10 Molecular Geometries and Bond Angles
  Molecular Geometry Worksheet
  Morphine  ---   Taxol   ---   Caffeine 
  Tamiflu   --- Check out the Molecular Playground
 
Homework:
Owl 3.10b Homework    Ideal Repulsion Shapes 10-27-15
3.10c Tutor   Determining Molecular Shapes 10-27-15
3.10d Exercise   Determining Molecular Shapes 10-27-15
3.10e Homework   Predicting Shapes of Molecules 10-27-15
3.10f Homework   Draw Lewis -- Predict Geometry 10-27-15
3.10g Homework   Given Lewis -- Predict Organic Geometry 10-27-15
3.10h Homework   Given Lewis -- Predict Angles 10-27-15
 
Announcements:
1. Lab   Third Lab - Saturday, October 24, 1:00-4:00pm
Tuesday
Oct 20
 
Lecture 11
Slides		 Lecture Material:
3.7 Drawing Lewis Structures of Covalent Compounds
  Organic Molecules
3.10 Molecular Geometries and Bond Angles
  Molecular Geometry Worksheet
  Morphine  ---   Taxol   ---   Caffeine 
 
Homework:
Owl 3.7i Homework    Lewis Structures from Space Filled 10-23-15
3.7j Homework   Lewis Structures from Formula 10-23-15
 
Announcements:
Thursday
Oct 15
 
Lecture 10
Slides		 Lecture Material:
3.7 Drawing Lewis Structures of Covalent Compounds
  Lewis Dot Worksheet
   Shortage of Electrons ... Multiple Bonds
3.9 Drawing Lewis Structures of Covalent Compounds
  Choices ... Resonance -- Simulation
3.8 Naming Binary Covalent Molecules
 
Homework:
Owl 3.9a Tutor    Resonance Structures  10-20-15
3.9b Homework    Resonance Structures 10-20-15
3.8b Homework    Naming Covalent Compounds 10-20-15
 
 Announcements:
Tuesday
Oct 13 		Academic Monday - No Class
Thursday
Oct 08
 
Lecture 9
Slides		 Lecture Material:
3.7 Drawing Lewis Structures --Simulation I -- Simulation II
  Lewis Dot Worksheet
  Bond Pair and Lone Pair Electrons
  Dealing With Cations and Anions
  Shortage of Electrons ... Multiple Bonds
 
Homework:
Owl 3.7b Tutor   Interpreting Lewis Structures 10-13-15
3.7c Tutor   Exceptions to Octet Rule 10-13-15
3.7d Homework   Interpret Lewis Structures 10-13-15
3.7e Homework   Lewis Structures 10-13-15
3.7f Exercise   Drawing Lewis Structures  10-13-15
3.7g Tutor    Drawing Lewis Structures  10-13-15
3.7h Homework    Drawing Lewis Structures  10-13-15
 
Announcements:
1. No Class   Tuesday, October 13 Academic Monday
Tuesday
Oct 06		 Exam I - ISB 135 - 1:00-2:15pm
Thursday
Oct 01
 
Lecture 8
Slides		 Lecture Material:
2.7 Electron Configuration and Preferred Charge
  Periodic Blocks
2.6 How Are the Electrons in an Atom Arranged
  Electron Configurations Worksheet-Completed
2.8 What Are Periodic Properties
  Brainaic Alkali Metal Movie
  Atomic Size ... Why is this?
  Ionization Energy
  Electronegativity
3.7 What Is a Covalent Bond and How Does One Form
  Bond Formation Pro's and Con's 
  
Homework:
Owl 2.7a Homework     Configurations & The Periodic Table  10-05-15
2.7b Homework   Main Group Electron Configurations 10-05-15
2.8a Simulation    Atomic Size 10-05-15
2.8b Homework     Atomic Size 10-05-15
2.8c Homework     Ionization Energy 10-05-15
 
 Announcements:
1. Lab   Second Lab - Saturday, October 3, 1:00-4:00pm
2. Exam I   Tuesday, October 6, In Class
Tuesday
Sep 29
 
Lecture 7
Slides		 Lecture Material:
2.6 How Are the Electrons in an Atom Arranged
  Shapes of Atomic Orbitals ... Atomic Orbital Worksheet
  Electron Configurations Worksheet
  Rules Governing Electron Configurations ... The Obital Stairway!!
  Electron Configurations ... Orbital Box ... Noble Gas ... Lewis Dot
  Electron Configurations ... Transition Metals

Homework:
Owl 2.6d Simulation Electron Configurations 10-02-15
2.6e Tutor Electron Configurations 2 10-02-15
2.6f Homework Electron Configurations of Atoms 10-02-15
2.6g Homework Electronic Configurations -- Noble Gas 10-02-15
2.6h Homework Valence Electrons and Lewis Dot 10-02-15
 
Announcements:
Thursday
Sep 24
 
Lecture 6
Slides		 Lecture Material:
4.4 How Do We Balance Chemical Equations
2.6 How Are the Electrons in an Atom Arranged
  Shapes of Atomic Orbitals ... Atomic Orbital Worksheet
  Electron Configurations Worksheet
  
Homework:
Owl 4.4d Tutor Balancing Chemical Equations 09-29-15
4.4e Homework Balancing Chemical Equations 09-29-15
4.4f Homework Balancing Combustion Reactions 09-29-15
4.4g Homework Balancing Reaction given Names 09-29-15
2.6a Homework Orbitals and Electrons 09-29-15
2.6b Homework Orbital Shapes 09-29-15
 
Announcements:
1. Lab   First Lab - Saturday, September 26, 1:00-4:00pm
Tuesday
Sep 22
 
Lecture 5
Slides		 Lecture Material:
How Do We Predict Formulas and Name Ionic Compounds
  Transition Metals
  Polyatomic Ions
4.3 What Is a Mole and How Do We Use It?
  Molar Mole ... What is it ... Just another conversion factor!
  Formula Weight ... Molar Mass
  Using the Mole to Calculate Mass Relationships
4.4 How Do We Balance Chemical Equations

C60 and beyond.

  
Homework:
Owl 3.6c Homework Naming -- TM 09-25-15
3.6e Homework Naming -- 1 09-25-15
3.6f Homework Naming -- 2 09-25-15
3.6g Homework Naming -- 3 09-25-15
3.6h Homework Naming -- All Types 09-25-15
4.3c Tutor Determining Molar Mass 09-25-15
4.3e Tutor Using Molar Mass 1 09-25-15
4.3f Tutor Using Molar Mass 2 09-25-15
4.3g Homework Mole/Mass Calculations 09-25-15
4.3h Homework Moles Vs Grams Calculations 09-25-15
  
Announcements:
1. Lab   First Lab - Saturday, September 26, 1:00-4:00pm
Thursday
Sep 17
 
Lecture 4
Slides		 Lecture Material:
2.5 What Is the Periodic Table ... How is it organized?
3.5 What is an Ionic Bond and What Holds it Together
  Coulomb's Law Data
3.6 How Do We Predict Formulas and Name Ionic Compounds
  Binary
  Transition Metals
   
Homework:
Owl 2.5b Homework The Periodic Table 09-22-15
2.5c Homework The Periodic Table -- Groups 09-22-15
2.5d Homework The Periodic Table -- Other 09-22-15
3.6a Tutor Naming Ionic Compound Formulas 09-22-15
3.6b Homework Naming -- Binary 09-22-15
 
 Announcements:
1. iClicker    iClicker for credit starts today.
Tuesday
Sep 15
 
Lecture 3
Slides		 Lecture Material:
3.5 How Do We Name Ionic Compounds -- A Brief Early Visit!
  Some Memorization
2.4 What Are Atoms Made Of
  Three Subatomic Particles
  Mass Number/Atomic Number
  Isotopes ... Determining Exact Mass
  Atomic Weight -- What is it?
2.5 What Is the Periodic Table ... How is it organized?
 
Homework:
Owl 2.4a Homework Subatomic Particles 09-18-15
2.4b Tutor Atomic Composition 09-18-15
2.4c Homework Atomic Composition and Isotopes 09-18-15
2.4f Homework Atomic Weight 09-18-15
2.5a Exercise Periodic Table Organization 09-18-15
   
Announcements:
1. iClicker    iClicker for credit starts on Thursday, September 17
         Register your iClicker in Owl by tonight.
Thursday
Sep 10
 
Lecture 2
Slides		 Lecture Material:
1.3 How do Scientists Report Numbers?
1.5 Factor-Label Method -- Dimensional Analysis -- Mathematics of Chemistry
3.5 How Do We Name Ionic Compounds -- A Brief Early Visit!
  Some Memorization
 
Homework:
Owl 1.3e Homework Significant Figures in a Number 09-15-15
1.3f Homework Significant Figures in Calculations 09-15-15
1.3g Homework Significant Figures and Errorless Numbers 09-15-15
1.5e Tutor Metric System Prefixes 09-15-15
1.5d Tutor Unit Conversions 09-15-15
1.5h Tutor Unit Conversions by the Factor-Label Method 09-15-15
1.5g Homework Metric Units: Unit Analysis  09-15-15
3.5b Simulation Ionic Compounds 09-15-15
iClicker Registration 09-15-15
  
Announcements:
Tuesday
Sep 08
 
Lecture 1
Slides		 Lecture Material:
General Course Information
  What Materials Do I Need
  Exam Dates & Grading
  Computer Resource Center
  Lab -- What/Where/When/What I Need to Know/Materials etc
  Some Fun With Balloons!
1.3 How do Scientists Report Numbers?
  
Homework:
Reading Ch 1.2 What is the Scientific Method
Ch 1.3 How do Scientists Report Numbers
Ch 1.4 How do we Make Measurements
Owl I.1a Navigation, Messages, and Browsers 09-11-15
I.1b Flash and eBook 09-11-15
I.2a Question Modes 09-11-15
I.2b Question Types 09-11-15
I.3a Chemical Formulas 09-11-15
I.3b Scientific Notation 09-11-15
I.3c Tables 09-11-15
 
Announcements:
1. Lab 1 Saturday September 26 1:00-4:00
Lab 2 Saturday October 3 1:00-4:00
Lab 3 Saturday October 24 1:00-4:00
Lab 4 Saturday October 31 1:00-4:00
Lab 5 Saturday November 14 1:00-4:00
Lab 6 Saturday December 5 1:00-4:00